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丙酮缩甘油

英文名: DL-1,2-Isopropylideneglycerol

CAS: 100-79-8      分子式: C6H12O3

分子量: 132.15800

别名:


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描述

Solketal is a protected form of glycerol with an isopropylidene acetal group joining two neighboring hydroxyl groups. Solketal contains a chiral center on the center carbon of the glycerol backbone, and so can be purchased as either the racemate or as one of the two enantiomers. Solketal has been used extensively in the synthesis of mono-, di- and triglycerides by ester bond formation. The free hydroxyl groups of solketal can be esterified with a carboxylic acid to form the protected monoglyceride, where the isopropylene group can then be removed using an acid catalyst in aqueous or alcoholic medium. The unprotected diol can then be esterified further to form either the di- or triglyceride.

基本信息
英文名:
DL-1,2-Isopropylideneglycerol
CAS号.:
100-79-8
别名:
(±)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylideneglycerol; 1,3-Dioxolane-4-methanol, 2,2-dimethyl-; 2,2-Dimethyl-1,3-dioxolane-4-methanol; Solketal; 1,2-O-Isopropylideneglycerol; 2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane; 1,2-Isopropylidene-rac-glycerol; (±)-2,2-Dimethyl-1,3-dioxolane-4-methanol;
分子式:
C6H12O3
分子量:
132.15800
PSA:
38.69000
LogP:
0.13020
物化属性
外观:
Liquid, Clear colorless
密度:
1.063
熔点:
-27℃
沸点:
188-189ºC
闪点:
80ºC
储存条件:
Sealed in dry,2-8°C
安全信息
海关编码:
29329970
WGK Germany:
2
危险类别码:
R36/37/38
安全说明:
S24/25
危险品标志:
Xi
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