英文名: (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
CAS: 76189-55-4 分子式: C46H36P2
分子量: 650.72600
别名:
Potent ligands for transition metal-catalyzed asymmetric reactions including hydrogenation and disilylation. 2,2′-Bis(diphenylphosphine)-1,1′-binaphthyl and its rhodium and ruthenium derivatives can be used as highly selective homogeneous catalysts for aryl ketones, β-ketoesters and α- Reduction of aminoketones. It can also be used for asymmetric hydrogenation of alkenes Chemicalbook and hydroformylation, asymmetric Heck reaction and asymmetric isomerization of allyl groups. Its Ag(I) complex can be used to catalyze the asymmetric aldol reaction between alkenyl trichloroacetate and aldehyde. Its Ag(I) complex can also be used to catalyze the asymmetric heterogeneous Diels-Alder reaction of azo compounds.