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R-1,1'-联-2-萘酚

英文名: (R)-(+)-1,1'-Bi-2-naphthol

CAS: 18531-94-7      分子式: C20H14O2

分子量: 286.32400

别名:


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描述

Atropine isomeric diols have many uses: auxiliary agents in asymmetric selective reduction of ketones; ligands in chiral titanium catalysts for stereoselective reactions, such as glyoxylic acid reactions, Diels-Alder reactions; A chiral auxiliary used to catalyze the asymmetric oxidation of sulfide to sulfoxide; chiral lanthanide trifluoromethanesulfonic acid is generated from binaphthol, which is used as a catalyst for asymmetric Diels-Alder reaction; Binaphthol derivatives, recently discovered for use in asymmetric Claisen rearrangements and asymmetric epoxidations; lithium aluminum hydride derivatives of these diols (BINAP-H), have been widely used in the reduction of ketones ; Chiral binaphthol salt precursor, salt for asymmetric reaction of olefin epoxidation.

基本信息
英文名:
(R)-(+)-1,1'-Bi-2-naphthol
CAS号.:
18531-94-7
别名:
(S)-(+)-1,1'-binaphthyl-2,2'-diol; (R)-(+)-2,2'-Dihydroxy-1,1'-dinaphthyl; BI-2-NAPHTHOL; (R)-(+)-1,1'-Bi(2-naphthol); 2,2'-DINAPHTHOL; (R)-(+)-2,2'-Dihydroxy-1,1'-binaphthyl; (R)-(+)-BINOL; (R)-(+)-1,1-Bi(2-Naphthol); (R)-(+)-1,1‘-Bi-2-naphthol; (R)-(+)-1,1'-Bi-2-naphtho; Dihydroxydinaphthylwhitepowder; (R)-[1,1'-Binaphthalene]-2,2'-diol; DI-B-NAPHTHOL; (R)-(+)-1,1'-Binaphthalene-2,2'-diol;
分子式:
C20H14O2
分子量:
286.32400
PSA:
40.46000
LogP:
5.07120
物化属性
外观:
white to off-white
密度:
1.301
熔点:
215-218 °C
沸点:
388.69°C (rough estimate)
闪点:
储存条件:
Store below +30°C.
安全信息
海关编码:
29071590
WGK Germany:
3
危险类别码:
25-36-36/37/38
安全说明:
26-45-24/25-36
危险品标志:
T,Xi
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